Single-crystal X-ray analysis of the ionic complex [(C5MedZ~CH2ph)J+[B(CHZph)(C~sdh~ow- s that no cation-anion bonding interactions exist, resulting in remarkable structural features in the highly electrophilic "naked cation, including an unprecedented y7-benzyl coordination.

A novel η7 coordination mode of a benzyl ligand in a cationic zirconium complex

PAPPALARDO D;
1994

Abstract

Single-crystal X-ray analysis of the ionic complex [(C5MedZ~CH2ph)J+[B(CHZph)(C~sdh~ow- s that no cation-anion bonding interactions exist, resulting in remarkable structural features in the highly electrophilic "naked cation, including an unprecedented y7-benzyl coordination.
cationic complex; x-ray structure; benzyl ligand
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/20.500.12070/5056
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